| title: |
| Hydrogen generation from the chemical energy carrier methanol: mechanistic insights
into the ruthenium-catalysed dehydrogenation reaction and the implementation of a
novel base-metal catalyst system |
|
| contributing persons: |
| Lydia Katharina Vogt[VerfasserIn] |
 |
1136291121 |
| Matthias Beller
, Prof. Dr.[AkademischeR BetreuerIn] |
|
112081908 |
|
Universität Rostock, Leibniz-Institut für Katalyse e. V. |
| Gabor Laurenczy
, Prof. Dr.[AkademischeR BetreuerIn] |
|
1089591187 |
|
École polytechnique fédérale de Lausanne, Institut des sciences et ingénierie chimiques |
|
| contributing corporate bodies: |
| Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
|
2147083-2 |
|
| |
| abstract: |
|
This thesis deals with the aqueous-phase reforming of methanol catalysed by homogeneous
pincer complexes. Based on extensive kinetic experiments, spectroscopic investigations
and supporting theoretical calculations, a complete mechanistic cycle could be proposed
for a Ru-pincer catalyst and its methylated derivative. Furthermore, a highly stable
catalyst system based on the base metal manganese was implemented for the low-temperature
dehydrogenation of methanol.
[English] |
|
| document type: |
|
| institution: |
| Faculty of Mathematics and Natural Sciences |
|
| language: |
|
| subject class (DDC): |
| 540 Chemistry & allied sciences |
|
| |
publication /
production: |
Rostock
|
Rostock: Universität Rostock
|
|
2017
|
|
| |
| identifiers: |
|
| |
| access condition: |
|
| license/rights statement: |
all rights reserved
This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
|
|
| RosDok id: |
rosdok_disshab_0000001744 |
| created / modified: |
28.06.2017 / 08.08.2023
|
| metadata license: |
The metadata of this document was dedicated to the public domain
(CC0 1.0 Universal Public Domain Dedication). |
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