Hydrogen generation from the chemical energy carrier methanol : mechanistic insights into the ruthenium-catalysed dehydrogenation reaction and the implementation of a novel base-metal catalyst system

Lydia Katharina Vogt

doi:10.18453/rosdok_id00001922

Lydia Katharina Vogt

Hydrogen generation from the chemical energy carrier methanol : mechanistic insights into the ruthenium-catalysed dehydrogenation reaction and the implementation of a novel base-metal catalyst system

Universität Rostock, 2017

https://doi.org/10.18453/rosdok_id00001922

Abstract: This thesis deals with the aqueous-phase reforming of methanol catalysed by homogeneous pincer complexes. Based on extensive kinetic experiments, spectroscopic investigations and supporting theoretical calculations, a complete mechanistic cycle could be proposed for a Ru-pincer catalyst and its methylated derivative. Furthermore, a highly stable catalyst system based on the base metal manganese was implemented for the low-temperature dehydrogenation of methanol.

Dissertation Freier Zugang

Titel:

Hydrogen generation from the chemical energy carrier methanol: mechanistic insights into the ruthenium-catalysed dehydrogenation reaction and the implementation of a novel base-metal catalyst system

Beteiligte Personen:

Lydia Katharina Vogt[VerfasserIn]
	1136291121
Matthias Beller , Prof. Dr.[AkademischeR BetreuerIn]
	112081908
	Universität Rostock, Leibniz-Institut für Katalyse e. V.
Gabor Laurenczy , Prof. Dr.[AkademischeR BetreuerIn]
	1089591187
	École polytechnique fédérale de Lausanne, Institut des sciences et ingénierie chimiques

Beteiligte Körperschaften:

Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution]
	2147083-2

Zusammenfassung:

This thesis deals with the aqueous-phase reforming of methanol catalysed by homogeneous pincer complexes. Based on extensive kinetic experiments, spectroscopic investigations and supporting theoretical calculations, a complete mechanistic cycle could be proposed for a Ru-pincer catalyst and its methylated derivative. Furthermore, a highly stable catalyst system based on the base metal manganese was implemented for the low-temperature dehydrogenation of methanol. [Englisch]

Dokumenttyp:

Dissertation

Einrichtung:

Mathematisch-Naturwissenschaftliche Fakultät

Sprache:

Englisch

Sachgruppe der DNB:

540 Chemie

Veröffentlichung /
Entstehung:

Rostock: Universität Rostock

2017

Identifikatoren: