title: |
Hydrogen generation from the chemical energy carrier methanol: mechanistic insights
into the ruthenium-catalysed dehydrogenation reaction and the implementation of a
novel base-metal catalyst system |
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contributing persons: |
Lydia Katharina Vogt[VerfasserIn] |
 |
1136291121 |
Matthias Beller
, Prof. Dr.[AkademischeR BetreuerIn] |
 |
112081908 |
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Universität Rostock, Leibniz-Institut für Katalyse e. V. |
Gabor Laurenczy
, Prof. Dr.[AkademischeR BetreuerIn] |
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1089591187 |
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École polytechnique fédérale de Lausanne, Institut des sciences et ingénierie chimiques |
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contributing corporate bodies: |
Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
 |
2147083-2 |
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abstract: |
This thesis deals with the aqueous-phase reforming of methanol catalysed by homogeneous
pincer complexes. Based on extensive kinetic experiments, spectroscopic investigations
and supporting theoretical calculations, a complete mechanistic cycle could be proposed
for a Ru-pincer catalyst and its methylated derivative. Furthermore, a highly stable
catalyst system based on the base metal manganese was implemented for the low-temperature
dehydrogenation of methanol.
[English] |
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document type: |
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institution: |
Faculty of Mathematics and Natural Sciences |
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language: |
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subject class (DDC): |
540 Chemistry & allied sciences |
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publication / production: |
Rostock
Rostock: Universität Rostock
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2017
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identifiers: |
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access condition: |
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license/rights statement: |
all rights reserved This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
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RosDok id: |
rosdok_disshab_0000001744 |
created / modified: |
28.06.2017 / 08.08.2023
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metadata license: |
The metadata of this document was dedicated to the public domain (CC0 1.0 Universal Public Domain Dedication). |