Transition metal-catalyzed carbonylation of nitrogen-containing heterocycles via C-H activation

Zechao Wang

doi:10.18453/rosdok_id00002099

Zechao Wang

Transition metal-catalyzed carbonylation of nitrogen-containing heterocycles via C-H activation

Universität Rostock, 2018

https://doi.org/10.18453/rosdok_id00002099

Abstract: The dissertation is mainly concerned with the development of transition metal-catalyzed carbonylation of nitrogen-containing compounds via C-H activation. We have described a palladium-catalyzed carbonylation of aromatic C-H bonds with alcohols using Mo(CO)6. We synthesized 3-methyleneisoindolin-1-ones and 2-phenylisoindolin-1-ones via C-H carbonylation using Mo(CO)6. A convenient procedure for the synthesis of 3-acylindoles has been established via C-H carbonylation. Furthermore, we have described a copper-catalyzed double carbonylation reaction using C6O6∙8H2O.

Dissertation Freier Zugang

Titel:

Transition metal-catalyzed carbonylation of nitrogen-containing heterocycles via C-H activation

Beteiligte Personen:

Zechao Wang[VerfasserIn]
	1161758518
Matthias Beller , Doctor[AkademischeR BetreuerIn]
	112081908
	Universität Rostock, Leibniz-Institut für Katalyse e. V.
Armin Börner , Doctor[AkademischeR BetreuerIn]
	131493663
	Universität Rostock, Leibniz-Institut für Katalyse e. V.

Beteiligte Körperschaften:

Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution]
	2147083-2

Zusammenfassung:

The dissertation is mainly concerned with the development of transition metal-catalyzed carbonylation of nitrogen-containing compounds via C-H activation. We have described a palladium-catalyzed carbonylation of aromatic C-H bonds with alcohols using Mo(CO)6. We synthesized 3-methyleneisoindolin-1-ones and 2-phenylisoindolin-1-ones via C-H carbonylation using Mo(CO)6. A convenient procedure for the synthesis of 3-acylindoles has been established via C-H carbonylation. Furthermore, we have described a copper-catalyzed double carbonylation reaction using C6O6∙8H2O. [Englisch]

Dokumenttyp:

Dissertation

Einrichtung:

Mathematisch-Naturwissenschaftliche Fakultät

Sprache:

Englisch

Sachgruppe der DNB:

540 Chemie

Veröffentlichung /
Entstehung:

Rostock

Rostock: Universität Rostock

2018