title: |
Selective oxidation of C16 macrocyclic diene to epoxides and ketones |
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contributing persons: |
Diego Alberto Jaime Treviño[VerfasserIn] |
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1149164220 |
Andreas Martin[AkademischeR BetreuerIn] |
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1024432599 |
Ulf Prüße[AkademischeR BetreuerIn] |
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122104986 |
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contributing corporate bodies: |
Universität Rostock[Grad-verleihende Institution] |
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38329-6 |
Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
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2147083-2 |
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abstract: |
In the present work, two approaches were followed in the oxidation of the macrocyclic
diene 1,9-cyclohexadecadiene. Firstly, an epoxidation using hydrogen peroxide as oxidant
was revised. A set of precursors used to form the peroxotungstophosphate active catalyst
and a set of phase transfer catalyst were screened. The conversion and selectivity
to the target epoxide varied pending on the precursor and PTC of choice. Secondly,
a Wacker-type oxidation was done using different palladium complexes. Among them,
a specific type of complexes showed a higher selectivity to the target ketone.
[English] |
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document type: |
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institution: |
Faculty of Mathematics and Natural Sciences |
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language: |
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subject class (DDC): |
540 Chemistry & allied sciences |
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publication / production: |
Rostock
Rostock: Universität Rostock
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2017
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statement of responsibility: |
vorgelegt von Lic. Diego A. Jaime Trevin̂o |
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identifiers: |
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access condition: |
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license/rights statement: |
all rights reserved This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
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RosDok id: |
rosdok_disshab_0000002008 |
created / modified: |
06.12.2018 / 08.08.2023
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metadata license: |
The metadata of this document was dedicated to the public domain (CC0 1.0 Universal Public Domain Dedication). |