Bio-based building blocks from 5-hydroxymethylfurfural via 1-hydroxyhexane-2,5-dione as intermediate

Bartosz Woźniak

doi:10.18453/rosdok_id00002403

Bartosz Woźniak

Bio-based building blocks from 5-hydroxymethylfurfural via 1-hydroxyhexane-2,5-dione as intermediate

Universität Rostock, 2018

https://doi.org/10.18453/rosdok_id00002403

Abstract: This dissertation reports on the synthesis and applications of the biomass-derived 1-hydroxyhexane-2,5-dione (HHD). A new catalytic process was developed for the hydrogenation/hydrolytic ring opening of 5-hydroxymethylfurfural (5-HMF) resulting in the formation of HHD in good yields. Furthermore, HHD was converted to useful follow-up products including pyrroles and cyclopentanone derivatives. Additionally, readily accessible rhenium(VII) oxide was used for the catalytic deoxydehydration of renewable triols under solvent-free and aerobic conditions resulting in formation of the hydroxy-alkenes.

Dissertation Freier Zugang

Titel:

Bio-based building blocks from 5-hydroxymethylfurfural via 1-hydroxyhexane-2,5-dione as intermediate

Beteiligte Personen:

Bartosz Woźniak[VerfasserIn]
	117790103X
Johannes Vries , de[AkademischeR BetreuerIn]
Katalin Barta[AkademischeR BetreuerIn]
	136114784

Beteiligte Körperschaften:

Universität Rostock[Grad-verleihende Institution]
	38329-6
Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution]
	2147083-2

Zusammenfassung:

This dissertation reports on the synthesis and applications of the biomass-derived 1-hydroxyhexane-2,5-dione (HHD). A new catalytic process was developed for the hydrogenation/hydrolytic ring opening of 5-hydroxymethylfurfural (5-HMF) resulting in the formation of HHD in good yields. Furthermore, HHD was converted to useful follow-up products including pyrroles and cyclopentanone derivatives. Additionally, readily accessible rhenium(VII) oxide was used for the catalytic deoxydehydration of renewable triols under solvent-free and aerobic conditions resulting in formation of the hydroxy-alkenes. [Englisch]

Dokumenttyp:

Dissertation

Einrichtung:

Mathematisch-Naturwissenschaftliche Fakultät

Sprache:

Englisch

Sachgruppe der DNB:

540 Chemie

Veröffentlichung /
Entstehung:

Rostock

Rostock: Universität Rostock

2018