Universität Rostock, 2018
Abstract: In this thesis, the synthesis of numerous di(triaryl phosphines) with DPE- or DBF-backbone was investigated using the well-known (-)-ephedrine methodology established by S. Jugé and co-workers. These di(triaryl phosphines) were tested in asymmetric catalysis and examined in regard to their stereochemical stability. Additionally, a new route for the synthesis of a P-chirogenic BINAP-type di(triaryl phosphine) was developed starting from a P-chirogenic secondary phosphine borane.
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