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Andranik Petrosyan

Multiple functionalizations of selected N-heterocycles by palladium-catalyzed cross-coupling reactions

Universität Rostock, 2019

Abstract: The presented dissertation deals with the multiple functionalization of several N-heterocycles via palladium-catalyzed cross-coupling reactions. In this regard, different polyalkynylated, polyalkenylated and polyarylated pyridine, pyrazine and naphthyridine derivatives were synthesized. Moreover, photophysical and electrochemical investigations of polyalkynylated compounds were carried out. In addition, various N-phenyl diarylpyrrols were synthesized by “ligand-free” palladium-catalyzed C–H activation. A probable mechanism was proposed.

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