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Reni Marie Elise Grauke

Identifizierung der Natur aktiver Chromkatalysatoren in der Tetramerisierung von Ethen mittels in situ Spektroskopie

Universität Rostock, 2019

https://doi.org/10.18453/rosdok_id00002702

Abstract: The 1-octene selectivity is strongly dependent on the nature of the precursor, the activator and the ligand. The catalyst development requires precise information about the formation of the actually active complexes and their influence on the catalytic performance. The aim is to analyze the effect of various AlR3 activators, ligands and different precursors on the nature of the catalytically active Cr species with the help of a tailored combination of spectroscopic in situ methods.

doctoral thesis   free access