goto contents


Patrick Piehl

Development of novel pincer catalysts for the synthesis of fine chemicals using hydrogen autotransfer reactions

Universität Rostock, 2019

https://doi.org/10.18453/rosdok_id00002703

Abstract: This thesis deals with the development of different homogeneous PNP pincer catalysts and their application in hydrogen autotransfer reactions. Manganese, rhenium and cyclometalated ruthenium complexes were used as catalysts for the α-alkylation of ketones with alcohols, a reaction creating new C‒C bonds while producing water as sole stochiometric by-product. This reaction was used for the alkylation of a broad scope of ketones including biologically relevant compounds like hormones with various alcohols.

doctoral thesis   free access    


Portals

OPACGVKDataCite Commons

Rights

all rights reserved

This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz).