Universität Rostock, 2020
https://doi.org/10.18453/rosdok_id00002708
Abstract: This thesis is mainly concerned with the carbonylative functionalization of unsaturated organic substrates in the presence of homogeneous catalysts. More specifically, oxidative carbonylation of alkynes, alkoxycarbonylation of 1,3-dienes and platinum-catalyzed alkoxycarbonylation of olefins are presented. The resulting esters, maleimides and adipic acid diesters constitute important intermediates for both organic synthesis and chemical industry. Regarding methodology developments, firstly a catalytic oxidative carbonylation reaction with air as a green oxidant was developed.
doctoral thesis free access
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.