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	0000-0003-3911-0816
	1215111045

Ji Yang

Palladium-catalyzed carbonylation of unsaturated carbon-carbon bonds

Universität Rostock, 2020

https://doi.org/10.18453/rosdok_id00002708

Abstract: This thesis is mainly concerned with the carbonylative functionalization of unsaturated organic substrates in the presence of homogeneous catalysts. More specifically, oxidative carbonylation of alkynes, alkoxycarbonylation of 1,3-dienes and platinum-catalyzed alkoxycarbonylation of olefins are presented. The resulting esters, maleimides and adipic acid diesters constitute important intermediates for both organic synthesis and chemical industry. Regarding methodology developments, firstly a catalytic oxidative carbonylation reaction with air as a green oxidant was developed.

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