| title: |
| Development of 3d metal catalysts for redox reactions |
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| contributing persons: |
|
| contributing corporate bodies: |
| Universität Rostock[Grad-verleihende Institution] |
 |
38329-6 |
| Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
|
2147083-2 |
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| |
| abstract: |
|
Herein is reported the application of non-noble metal-based catalytic systems for
the homogeneous oxidation of organic substrates using air, specifically in amines
and N-heterocycles. Simple 3d metal salts have been used, in combination with N-ligands,
to facilitate the oxidative cleavage of C(sp3)–C(sp3) bonds. These reactions have
been studied, using spectroscopic methods, to propose plausible mechanistic pathways.
We believe such deconstructive strategies can enable late-stage functionalisation
of pharmaceuticals and the synthesis of drug metabolites.
[English] |
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| document type: |
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| institution: |
| Faculty of Mathematics and Natural Sciences |
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| language: |
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| subject class (DDC): |
| 500 Natural sciences |
| 540 Chemistry & allied sciences |
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| |
publication /
production: |
Rostock
|
Rostock: Universität Rostock
|
|
2021
|
|
| statement of responsibility: |
| vorgelegt von David Leonard |
|
| notes: |
| Enthält Zeitschriftenartikel |
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| |
| identifiers: |
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| |
| access condition: |
|
| license/rights statement: |
all rights reserved
This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
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|
| RosDok id: |
rosdok_disshab_0000002693 |
| created / modified: |
17.02.2022 / 08.08.2023
|
| metadata license: |
The metadata of this document was dedicated to the public domain
(CC0 1.0 Universal Public Domain Dedication). |
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