title: |
Influence of the pore structure on the catalytic performance of Rh-supported Zr-MOFs
in the hydroformylation of olefins |
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contributing persons: |
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contributing corporate bodies: |
Universität Rostock[Grad-verleihende Institution] |
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38329-6 |
Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
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2147083-2 |
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abstract: |
Zirconium-based metal-organic frameworks (Zr-MOFs) of different pore sizes and structure
were synthesized and used for the preparation of the Rh-supported catalysts. The catalytic
performance was studied in the hydroformylation of olefins to the corresponding aldehydes.
A series of n-alk-1-enes of different chain length and bulky olefins with different
size was used to study the influence of the pore size and structure. The results show
that the Zr-MOF-based catalysts are very active and show high aldehyde selectivity.
[English] |
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document type: |
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institution: |
Faculty of Mathematics and Natural Sciences |
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language: |
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subject class (DDC): |
540 Chemistry & allied sciences |
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publication / production: |
Rostock
Rostock: Universität Rostock
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2020
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statement of responsibility: |
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identifiers: |
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access condition: |
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license/rights statement: |
all rights reserved This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
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RosDok id: |
rosdok_disshab_0000002722 |
created / modified: |
08.04.2022 / 08.08.2023
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metadata license: |
The metadata of this document was dedicated to the public domain (CC0 1.0 Universal Public Domain Dedication). |