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Maximilian Marx

Investigations on carbon dioxide reduction and CO2 reductive coupling facilitated by Fe and Cu complexes

Universität Rostock, 2020

https://doi.org/10.18453/rosdok_id00003573

Abstract: Herein, investigations on photocatalytic carbon dioxide reduction and CO2 reductive coupling with Fe and Cu complexes are described. Photocatalytic CO2 reduction to CO and HCOOH with Cu photosensitizers combined with Fe catalysts was studied. In addition, the reductive coupling of CO2 to oxalate by a Fe and various Cu complexes bearing multidentate ligands was evaluated. Based on these results, the importance of cautious analysis and consideration of competing reactions were highlighted. This work could serve as a valuable guideline for future investigations on CO2 reductive coupling.

Dissertation   Freier Zugang