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Mareike Hüttenschmidt

Koordinationschemische Gerüstverbindungen für lichtinduzierte Elektronentransferprozesse

Universität Rostock, 2022

https://doi.org/10.18453/rosdok_id00003911

Abstract: In this work, redox-active side-on coordinated W-alkyne complexes of the type [Tp*W(CO)Br((C5H4N)CCE)] (E = CH3, CH2-PPh2, PPh2) were synthesized and subsequently coordinated to metal centers (M = Ir, Ru, Pd). In the second part of this work, NAD/NADH model ligands based on 1,10-phenanthroline were synthesized and investigated within iridium and ruthenium coordination compounds. The different ligand systems were characterized spectroscopically and their suitability as components in coordination compounds undergoing light-induced electron transfer reactions were discussed.

doctoral thesis   free access    

title:
Koordinationschemische Gerüstverbindungen für lichtinduzierte Elektronentransferprozesse
contributing persons:
Mareike Hüttenschmidt[VerfasserIn]
1266026177
Wolfram Seidel[AkademischeR BetreuerIn]
115237585
Berthold Kersting[AkademischeR BetreuerIn]
172666589
Universität Leipzig
contributing corporate bodies:
Universität Rostock[Grad-verleihende Institution]
38329-6
Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution]
2147083-2
 
abstract:
Es wurden zum einen redox-aktive side-on koordinierte W-Alkinkomplexe des Typs [Tp*W(CO)Br((C5H4N)CCE)] (E = CH3, CH2-PPh2, PPh2) synthetisiert und anschließend an Metallzentren (M = Ir, Ru, Pd) koordiniert. Zum anderen wurden NAD/NADH-Modell-Liganden auf der Basis von 1,10-Phenanthrolin synthetisiert und als Bestandteile von Ir- und Ru-Komplexverbindungen genauer betrachtet. Die unterschiedlichen Ligandensysteme wurden umfassend spektroskopisch charakterisiert und ihre Eignung als Bestandteile von Komplexverbindungen, die lichtinduzierte Elektronentransferreaktionen eingehen, beurteilt. [German]
In this work, redox-active side-on coordinated W-alkyne complexes of the type [Tp*W(CO)Br((C5H4N)CCE)] (E = CH3, CH2-PPh2, PPh2) were synthesized and subsequently coordinated to metal centers (M = Ir, Ru, Pd). In the second part of this work, NAD/NADH model ligands based on 1,10-phenanthroline were synthesized and investigated within iridium and ruthenium coordination compounds. The different ligand systems were characterized spectroscopically and their suitability as components in coordination compounds undergoing light-induced electron transfer reactions were discussed. [English]
document type:
doctoral thesis
institution:
Faculty of Mathematics and Natural Sciences
language:
German
subject class (DDC):
500 Natural sciences
540 Chemistry & allied sciences
 
publication /
production:		 Rostock
Rostock: Universität Rostock
2022
statement of responsibility:
vorgelegt von Mareike Hüttenschmidt
 
identifiers:
K10plus id: 181491644X
URN: urn:nbn:de:gbv:28-rosdok_id00003911-8
DOI: 10.18453/rosdok_id00003911
PURL: https://purl.uni-rostock.de/rosdok/id00003911
 
access condition:
open access
license/rights statement:
all rights reserved
This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz).
RosDok id: rosdok_disshab_0000002799
created / modified: 22.08.2022 / 08.08.2023
metadata license: The metadata of this document was dedicated to the public domain
(CC0 1.0 Universal Public Domain Dedication).
fulltext

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https://doi.org/
10.18453/rosdok_id00003911

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