| title: |
| Value-added products from bio-based platform chemicals |
|
| contributing persons: |
| Andrea Dell'Acqua[VerfasserIn] |
 |
0000-0003-1546-0045 |
 |
1275617875 |
| Johannes G. Vries
, de[AkademischeR BetreuerIn] |
|
132252880 |
| Gert-Jan Gruter[AkademischeR BetreuerIn] |
|
Faculty of Science Van 't Hoff Institute for Molecular Sciences, University of Amsterdam |
|
| contributing corporate bodies: |
| Universität Rostock[Grad-verleihende Institution] |
|
38329-6 |
| Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
|
2147083-2 |
|
| |
| abstract: |
|
This thesis describes the use of platform-derived chemicals as novel, bio-based intermediates
to the synthesis of value-added compounds. Levulinic acid-derived angelica lactones
were used to preapre C3 chemicals such as malonic acid via ozonolysis and novel poly-norbornene-like
polymers. Glycolaldehyde, obtained from lignocellulose, was employed for the first
time as C1 building block for the N-formylation of secondary amines by catalyst-free
radical oxidation. Methyl vinyl glycolate, a side stream product of the production
of lactate from sugars, was used as precursor for bio-based polyester.
[English] |
|
| document type: |
|
| institution: |
| Faculty of Mathematics and Natural Sciences |
|
| language: |
|
| subject class (DDC): |
| 540 Chemistry & allied sciences |
|
| |
publication /
production: |
Rostock
|
Rostock: Universität Rostock
|
|
2022
|
|
| statement of responsibility: |
| vorgelegt von Andrea Dell'Acqua |
|
| notes: |
| Enthält Zeitschriftenartikel |
|
| |
| identifiers: |
|
| |
| access condition: |
|
| license/rights statement: |
all rights reserved
This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
|
|
| RosDok id: |
rosdok_disshab_0000002859 |
| created / modified: |
15.12.2022 / 08.08.2023
|
| metadata license: |
The metadata of this document was dedicated to the public domain
(CC0 1.0 Universal Public Domain Dedication). |
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