| title: |
| Hydrogen / deuterium exchange reactions: small variations for heavy changes |
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| contributing persons: |
|
| contributing corporate bodies: |
| Universität Rostock[Grad-verleihende Institution] |
 |
38329-6 |
| Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
|
2147083-2 |
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| |
| abstract: |
|
This dissertation reports the development of new catalytic methodologies for deuterium
incorporation into organic molecules. In a first part, the use of a simple Lewis acid
is reported for the isotopic labelling of electron-rich (hetero)arenes. Next, two
heterogeneous catalysts are presented for the labelling of comparable compounds: a
first-generation iron-based system and a follow-up work using manganese. Both materials
are easily prepared and fully characterised. Additionally, investigations were performed
to gain insight on the mechanisms.
[English] |
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| document type: |
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| institution: |
| Faculty of Mathematics and Natural Sciences |
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| language: |
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| subject class (DDC): |
| 540 Chemistry & allied sciences |
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| |
publication /
production: |
Rostock
|
Rostock: Universität Rostock
|
|
2022
|
|
| statement of responsibility: |
| vorgelegt von Florian Marwan Bourriquen |
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| notes: |
| Enthält Zeitschriftenartikel |
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| |
| identifiers: |
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| |
| access condition: |
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| license/rights statement: |
all rights reserved
This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
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|
| RosDok id: |
rosdok_disshab_0000002967 |
| created / modified: |
18.05.2023 / 08.08.2023
|
| metadata license: |
The metadata of this document was dedicated to the public domain
(CC0 1.0 Universal Public Domain Dedication). |
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