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Nora Isabel Cosima Jannsen

Rhodiumkomplex katalysierte Addition von Nukleophilen an terminale Alkine und Allene

Universität Rostock, 2023

Abstract: This thesis deals in detail with the causes of activity, inhibition and deactivation of catalysis using the example of various rhodium complex catalysed reactions. For this purpose, the upstream equilibrium of the Michaelis-Menten equation and the effect of different solvents on the activity of the catalysis are analysed. The knowledge gained was applied to the catalytic couplings of alkynes or allenes with nucleophiles developed by Breit et al. which were investigated mechanistically and complex chemically.

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