| title: |
| On the role of nitride and oxide supports for the charge state of isolated palladium
catalysts |
|
| contributing persons: |
| Junhao Huang[VerfasserIn] |
 |
135054597X |
| Jennifer Strunk[AkademischeR BetreuerIn] |
|
13425810X |
|
Leibniz-Institut für Katalyse e.V. |
| Alexander A. Auer[AkademischeR BetreuerIn] |
|
123929954 |
| Andrew Logsdail[AkademischeR BetreuerIn] |
|
Cardiff University |
|
| contributing corporate bodies: |
| Universität Rostock[Grad-verleihende Institution] |
|
38329-6 |
| Universität Rostock. Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
|
2147083-2 |
|
| |
| abstract: |
|
In this dissertation, a series of isolated palladium catalysts were constructed, and
the effect of support type, including oxide and nitride supports, on the charge state
of the palladium center was investigated. Based on the periodic trend in electronegativity,
a correlation was established between the formal oxidation state, computed Bader charge,
and CO vibrational frequency, allowing the identification of appropriate models to
better understand the coordination and electronic structure of palladium sites.
[English] |
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| document type: |
|
| institution: |
| Faculty of Mathematics and Natural Sciences |
|
| language: |
|
| subject class (DDC): |
| 540 Chemistry & allied sciences |
|
| extent: |
|
1 Online-Ressource (XVIII, 157 Seiten)
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|
| |
publication /
production: |
Rostock
|
Rostock: Universität Rostock
|
|
17. April 2023
(normalised date: 2023) |
|
| statement of responsibility: |
| vorgelegt von Junhao Huang |
|
| |
| identifiers: |
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| |
| access condition: |
|
| license/rights statement: |
all rights reserved
This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
|
|
| RosDok id: |
rosdok_disshab_0000003205 |
| created / modified: |
09.12.2024 / 10.12.2024
|
| metadata license: |
The metadata of this document was dedicated to the public domain
(CC0 1.0 Universal Public Domain Dedication). |
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