On the role of nitride and oxide supports for the charge state of isolated palladium catalysts

Junhao Huang

doi:10.18453/rosdok_id00004707

Junhao Huang

On the role of nitride and oxide supports for the charge state of isolated palladium catalysts

Universität Rostock, 17. April 2023

https://doi.org/10.18453/rosdok_id00004707

Abstract: In this dissertation, a series of isolated palladium catalysts were constructed, and the effect of support type, including oxide and nitride supports, on the charge state of the palladium center was investigated. Based on the periodic trend in electronegativity, a correlation was established between the formal oxidation state, computed Bader charge, and CO vibrational frequency, allowing the identification of appropriate models to better understand the coordination and electronic structure of palladium sites.

Dissertation Freier Zugang

Titel:

On the role of nitride and oxide supports for the charge state of isolated palladium catalysts

Beteiligte Personen:

Junhao Huang[VerfasserIn]
	135054597X
Jennifer Strunk[AkademischeR BetreuerIn]
	13425810X
	Leibniz-Institut für Katalyse e.V.
Alexander A. Auer[AkademischeR BetreuerIn]
	123929954
Andrew Logsdail[AkademischeR BetreuerIn]
	Cardiff University

Beteiligte Körperschaften:

Universität Rostock[Grad-verleihende Institution]
	38329-6
Universität Rostock. Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution]
	2147083-2

Zusammenfassung:

In this dissertation, a series of isolated palladium catalysts were constructed, and the effect of support type, including oxide and nitride supports, on the charge state of the palladium center was investigated. Based on the periodic trend in electronegativity, a correlation was established between the formal oxidation state, computed Bader charge, and CO vibrational frequency, allowing the identification of appropriate models to better understand the coordination and electronic structure of palladium sites. [Englisch]

Dokumenttyp:

Dissertation

Einrichtung:

Mathematisch-Naturwissenschaftliche Fakultät

Sprache:

Englisch

Sachgruppe der DNB:

540 Chemie

Umfang:

1 Online-Ressource (XVIII, 157 Seiten)

Veröffentlichung /
Entstehung:

Rostock: Universität Rostock