| title: |
| Synthesis of heterocyclazines by Buchwald-Hartwig reaction and C-H activation |
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| contributing persons: |
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| contributing corporate bodies: |
| Universität Rostock[Grad-verleihende Institution] |
 |
38329-6 |
| Universität Rostock. Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
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2147083-2 |
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| abstract: |
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This dissertation focuses on the development of methods for synthesizing new N- and
O-doped aceanthrylene derivatives as well as N-doped azulenefluorene derivatives.
The synthesis strategy employs Buchwald–Hartwig reactions and/or C–H activation for
cyclization. In the process, C–C and C–N bonds are formed, yielding novel heterocycl[3.3.2]azines
and heterocycl[4.2.2]azines. In addition, theoretical studies on aromaticity and energy
levels, as well as experimental analyses of the electronic and optical properties,
are conducted.
[English] |
|
In dieser Dissertation werden Methoden zur Entwicklung neuer N- und O-dotierter Aceanthrylene
sowie N-dotierter Azulenofluorene, entwickelt. Als Synthesestrategie kommen Buchwald-Hartwig-Reaktionen
und/oder C–H-Aktivierungen zur Cyclisierung zum Einsatz. Dabei werden C–C- und C–N-Bindungen
gebildet und neuartige Heterocycl[3.3.2]azine sowie Heterocycl[4.2.2]azine erhalten.
Ergänzend werden theoretische Untersuchungen zur Aromatizität und zu Energieniveaus
sowie experimentelle Analysen der elektronischen und optischen Eigenschaften durchgeführt.
[German] |
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| document type: |
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| institution: |
| Faculty of Mathematics and Natural Sciences |
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| language: |
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| subject class (DDC): |
| 540 Chemistry & allied sciences |
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| extent: |
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1 Online-Ressource (verschiedene Seitenzählungen)
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publication /
production: |
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Rostock: Universität Rostock
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30.10.2025
(normalised date: 2025) |
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| statement of responsibility: |
| vorgelegt von Jan Radolko |
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| notes: |
| Enthält Zeitschriftenartikel |
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| identifiers: |
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| access condition: |
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| license/rights statement: |
all rights reserved
This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
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| RosDok id: |
rosdok_disshab_0000003684 |
| created / modified: |
13.10.2026 / 14.10.2026
|
| metadata license: |
The metadata of this document was dedicated to the public domain
(CC0 1.0 Universal Public Domain Dedication). |
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