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Christian Fischer

UV-vis-Spektroskopie in der homogenen Katalyse - Komplexchemische Untersuchungen an Rhodium-Katalysatoren

Universität Rostock, 2010

https://doi.org/10.18453/rosdok_id00000719

Abstract: Kinetic investigations were carried out for transition metal complexes of rhodium, hafnium, and zirconium using UV-vis spectroscopy. Central aspects were the determination of pre-hydrogenation times for diolefin hydrogenations of rhodium diolefin complexes of the type [Rh(PP*)COD][BF4] (PP* = chiral diphosphane), and the determination of stability constants of arene complexes of the type [Rh(PP*)η-arene][BF4].

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