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Henry Postleb Dr.

Reaktionstechnische Analyse der Hydroformylierung von Olefingemischen

Universität Rostock, 2010

Abstract: A novel activity control concept was developed for a ligand modified rhodium catalyst in a continuous industrial hydroformylation process by addition of an olefin with known kinetics. Therefore, five different alkenes were studied, separately and in the mixture, in two solvents. The effects of temperature, pressure, rhodium concentration and ligand/rhodium ratio on the rates of hydroformylation in the olefin mixture were investigated. In addition, a rate model for calculation of the active catalyst species concentration was developed based on the kinetic data.

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