title: |
Infrared Laser Driven Quantum Dynamics of Double Proton Transfer Reactions and Collective
Carbonyl Vibrations |
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contributing persons: |
Mahmoud Abdel-Latif[VerfasserIn] |
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1016859708 |
Oliver Kühn
, Prof. Dr.[AkademischeR BetreuerIn] |
Ralf Ludwig
, Prof. Dr.[AkademischeR BetreuerIn] |
Volkhard May
, PD. Dr.[AkademischeR BetreuerIn] |
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contributing corporate bodies: |
Universität Rostock, Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
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2147083-2 |
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abstract: |
Laser control of ultrafast double proton transfer is investigated for a two-dimensional
model for asymmetrically substituted porphycene by means of an infrared pump-dump
scheme. Based on the orientation of the transition dipole moments the tautomerization
control may lead to an estimated change in the Förster transfer coupling between chromophors
of molecular wires of about 60%. The excitation of the degenerate E1 carbonyl stretching
vibrations in dimanganese decacarbonyl using circularly polarized laser is shown to
trigger wave packet circulation in the subspace of these two modes. A 2D-dissociative
PES for CO group is discussed.
[English] |
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document type: |
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institution: |
Faculty of Mathematics and Natural Sciences |
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language: |
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subject class (DDC): |
540 Chemistry & allied sciences |
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publication / production: |
Rostock
Rostock: Universität Rostock
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2011
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identifiers: |
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access condition: |
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license/rights statement: |
all rights reserved This work may only be used under the terms of the German Copyright Law (Urheberrechtsgesetz). |
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RosDok id: |
rosdok_disshab_0000000717 |
created / modified: |
13.10.2011 / 08.08.2023
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metadata license: |
The metadata of this document was dedicated to the public domain (CC0 1.0 Universal Public Domain Dedication). |