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Lukas Chojetzki

Untersuchungen an neuartigen Derivaten des Singulett-Biradikals [P(µ-NTer)]2

Universität Rostock, 2020

Abstract: In this dissertation, the results of the investigations on the reactivity of the known singlet biradical [P(µ-NTer)]2 are presented and explained. The reactivity towards dienes and diynes, diazomethanes and bromoalkanes was investigated. Also, first reactions were carried out with a Brønsted acid, which has a weakly coordinating anion. The resulting novel compounds were characterized by analytical methods such as NMR, IR and Raman spectroscopy, mass spectrometry and single crystal X-ray structural analysis.

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