| title: |
| Bio-inspired sustainable catalysis with base-metals and visible light |
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| contributing persons: |
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| contributing corporate bodies: |
| Universität Rostock[Grad-verleihende Institution] |
 |
38329-6 |
| Universität Rostock. Mathematisch-Naturwissenschaftliche Fakultät[Grad-verleihende Institution] |
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2147083-2 |
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| abstract: |
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This thesis explores biomimetic catalytic systems inspired by metalloenzymes, utilizing
ligand-to-metal charge transfer (LMCT) and metal-ligand cooperation (MLC) to enable
efficient 3d-metal catalysis. By using earth-abundant metals, these approaches mimic
enzymatic mechanisms where ligands actively participate in reactions. It covers cobalt
catalysis for visible-light-induced radical desaturation and manganese pincer complexes
for various redox transformations. The research integrates experimental and theoretical
studies to optimize sustainable catalytic systems.
[English] |
|
Diese Habilitationsschrift untersucht biomimetische Katalysesysteme, inspiriert von
Metalloenzymen, die Ligand-zu-Metall-Ladungsübertragung (LMCT) und Metall-Ligand-Kooperation
(MLC) nutzen, um effiziente 3d-Metallkatalyse zu ermöglichen. Durch den Einsatz erdreichter
Metalle ahmen diese Ansätze enzymatische Mechanismen nach, bei denen Liganden aktiv
an Reaktionen teilnehmen. Sie umfasst Kobaltkatalyse für lichtinduzierte Radikaldesaturierungen
und Mangan-Pincer-Komplexe für verschiedene Redox-Transformationen.
[German] |
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| document type: |
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| institution: |
| Faculty of Mathematics and Natural Sciences |
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| language: |
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| subject class (DDC): |
| 540 Chemistry & allied sciences |
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| extent: |
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1 Online-Ressource (verschiedene Seitenzählungen)
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publication /
production: |
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Rostock: Universität Rostock
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2025
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|
| statement of responsibility: |
| vorgelegt von Dr. Osama El-Sepelgy |
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| notes: |
| Enthält Zeitschriftenartikel |
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| identifiers: |
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| access condition: |
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| license/rights statement: |
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| RosDok id: |
rosdok_disshab_0000003451 |
| created / modified: |
06.03.2026 / 06.03.2026
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| metadata license: |
The metadata of this document was dedicated to the public domain
(CC0 1.0 Universal Public Domain Dedication). |
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