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Santiago Sebastian Gonzalez

Development and evaluation of heterogeneous catalysts for the reforming of methane-rich gases to synthesis gas

Universität Rostock, 13.11.2024

https://doi.org/10.18453/rosdok_id00005267

Abstract: This thesis explores biogas valorization into syngas via methane reforming using 2.5 wt.% Ni on MgO-Al₂O₃ catalysts, aiming greener downstream applications. Catalyst deactivation via coking, poisoning, and re-oxidation were the main challenges. Therefore, various formulations were designed to optimize key features of the catalysts. A novel MgO-Al₂O₃ support (WI.800) was developed, which led to materials with higher activity and coke resistance vs. commercial counterparts. Thus, NiLaGa/WI.800 outstood in methane reforming and impurity tolerance, displaying real-world application potential.

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