Universität Rostock, 2013
Abstract: One part is about the access to a new type of an 1,2-dithiolene-ligand expanded by an 1,2,3-triazole moiety. The electronic properties of the resulting complexes are influenced in the same manner as with benzene-1,2-dithiolate. Another aspect deals with the combination of a dithiolene function with the bidentate nitrogen donor group in the 1,10-phenanthroline-5,6-dithiolate. By means of dinuclear complexes with photocentres investigations on the life times of the excited states were made to discuss the type and the direction of the electron and energy transfer processes, respectively.
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