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Rajesh Dasi

Thermal and photocatalytic C-C and C-N bond formation by atom-transfer radical additions and photocycloadditions

Universität Rostock, 2023

https://doi.org/10.18453/rosdok_id00004745

Abstract: The content of this thesis is presented in three parts. In the first part, the radical functionalisation of biomass-derived 5-chloromethylfurfural (CMF) was described. In the second part, visible light-mediated triplet-sensitized [2+2] and [3+2] photocycloadditions of 2-cyanochromone with several alkenes were demonstrated using Iridium photocatalyst. The last part describes the a photocatalytic one-pot dehydrogenative Aza Paternò-Büchi reaction of dihydroquinoxalinones with substituted styrenes and acrylonitriles for the synthesis of diverse functionalised azetidine derivatives.

doctoral thesis   free access