Universität Rostock, 2024
https://doi.org/10.18453/rosdok_id00005135
Abstract: This dissertation investigates the broad potential of cobalt catalysis in open-shell transformations, positioning cobalt as a sustainable, versatile alternative to noble metals for conducting complex organic reactions under mild conditions. The thesis is organized into four projects, each contributing unique insights into cobalt's role in radical desaturation and selective functionalization of various organic molecules. The combination of both experimental and theoretical approach delivered a comprehensive understanding of cobalt’s reactivity and selectivity.
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